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arXiv · 2301.11672

Excitons and trions with negative effective masses in two-dimensional semiconductors

M. A. Semina·J. V. Mamedov·M. M. Glazov
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Abstract

We study theoretically fundamental Coulomb-correlated complexes: neutral and charged excitons, also known as trions, in transition metal dichalogenides monolayers. We focus on the situation where one of the electrons occupies excited, high-lying, conduction band characterized by a negative effective mass. We develop the theory of such high-lying excitons and trions with negative effective mass and demonstrate the key role of the non-parabolicity of the high-lying conduction band dispersion in formation of the bound exciton and trion states. We present simple, accurate and physically justified trial wavefunctions for calculating the binding energies of Coulomb-bound complexes and compare the results of variational calculations with those of a fully numerical approach. Within the developed model we discuss recent experimental results on observation of high-lying negative effective mass trions [K.-Q. Lin et al., Nat. Commun. 13, 6980 (2022)].

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M. A. Semina, J. V. Mamedov, M. M. Glazov. 2023-03-22. Excitons and trions with negative effective masses in two-dimensional semiconductors. https://doi.org/10.1093/oxfmat%2Fitad004

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