Moss-like growth of metal electrodes: On the role of competing faradaic reactions and fast-charging

Abstract

Uncontrolled crystal growth during electroreduction of reactive metals in liquid electrolytes produces porous, low-density, mossy metal deposits that grow primarily along the surface normal vector to a planar electrode substrate. The moss-like deposits are fragile and cause premature failure of batteries by chemical, physical, and mechanical pathways. Here we use electroanalytical Rotating-Disk Electrode (RDE) studies in a three-electrode electrochemical cell to elucidate the fundamental origin of moss-like growth of metals. We report that competing Faradaic reactions occurring on the electrode surface is the source of the phenomenon. On this basis, we conclude that a moss-like growth regime can be accessed during electrodeposition of any metal by subtle shifts in electrolyte chemistry and deposition rate. Specifically, for Zn, a metal that conventionally is not known to form moss-like electrodeposits, obvious moss-like deposition patterns emerge at low-current densities in strongly-alkaline electrolytes that undergo electroreduction to form an interphase on the electrodeposited Zn. Conversely, we find that under conditions where the rate of metal electroplating is large relative to that of other competing Faradaic reactions, it is possible to eliminate the mossy-like growth regime for Zn. Taken together, our findings open up a new approach for simultaneously achieving favorable metal deposition morphology and fast charging in next-generation batteries using metal anodes.