Size Effect and Scaling in Quasi-static and Fatigue Fracture of Graphene Polymer Nanocomposites

Abstract

This work investigated how the structure size affects the quasi-static and fatigue behaviors of graphene polymer nanocomposites, a topic that has been often overlooked. The results showed that both quasi-static and fatigue failure of these materials scale nonlinearly with the structure size due to the presence of a significant Fracture Process Zone (FPZ) ahead of the crack tip induced by graphene nanomodification. Such a complicated size effect and scaling in either quasi-static or fatigue scenario cannot be described by the Linear Elastic Fracture Mechanics (LEFM), but can be well captured by the Size Effect Law (SEL) which considers the FPZ. Thanks to the SEL, the enhanced quasi-static and fatigue fracture properties were properly characterized and shown to be independent of the structure size. In addition, the differences on the morphological and mechanical behaviors between quasi-static fracture and fatigue fracture were also identified and clarified in this work. The experimental data and analytical analyses reported in this paper are important to deeply understand the mechanics of polymer-based nanocomposite materials and even other quasi-brittle materials (e.g., fiber-reinforced polymers or its hybrid with nanoparticles, etc.), and further advance the development of computational models capable of capturing size-dependent fracture of materials in various loading conditions.