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arXiv · 2305.08538

Ultrasound cavitation and exfoliation dynamics of 2D materials re-vealed in operando by X-ray free electron laser megahertz imaging

Kang Xiang·Shi Huang·Hongyuan Song·Vasilii Bazhenov·Valerio Bellucci·Sarlota Birnsteinova·Raphael de Wijn·Jayanath C. P. Koliyadu·Faisal H. M. Koua·Adam Round·Ekaterina Round·Abhisakh Sarma·Tokushi Sato·Marcin Sikorski·Yuhe Zhang·Eleni Myrto Asimakopoulou·Pablo Villanueva-Perez·Kyriakos Porfyrakis·Iakovos Tzanakis·Dmitry G. Eskin·Nicole Grobert·Adrian Mancuso·Richard Bean·Patrik Vagovic·Jiawei Mi
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Abstract

Ultrasonic liquid phase exfoliation is a promising method for the production of two-dimensional (2D) layered materials. A large number of studies have been made in investigating the underlying ultrasound exfoliation mechanisms. However, due to the experimental challenges for capturing the highly transient and dynamic phenomena in real-time at sub-microsecond time and micrometer length scales simultaneously, most theories reported to date still remain elusive. Here, using the ultra-short X-ray Free Electron Laser pulses (~25ps) with a unique pulse train structure, we applied MHz X-ray Microscopy and machine-learning technique to reveal unambiguously the full cycles of the ultrasound cavitation and graphite layer exfoliation dynamics with sub-microsecond and micrometer resolution. Cyclic fatigue shock wave impacts produced by ultrasound cloud implosion were identified as the dominant mechanism to deflect and exfoliate graphite layers mechanically. For the graphite flakes, exfoliation rate as high as ~5 angstroms per shock wave impact was observed. For the HOPG graphite, the highest exfoliation rate was ~0.15 angstroms per impact. These new findings are scientifically and technologically important for developing industrial upscaling strategies for ultrasonic exfoliation of 2D materials.

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Kang Xiang, Shi Huang, Hongyuan Song, Vasilii Bazhenov, Valerio Bellucci, Sarlota Birnsteinova, Raphael de Wijn, Jayanath C. P. Koliyadu, Faisal H. M. Koua, Adam Round, Ekaterina Round, Abhisakh Sarma, Tokushi Sato, Marcin Sikorski, Yuhe Zhang, Eleni Myrto Asimakopoulou, Pablo Villanueva-Perez, Kyriakos Porfyrakis, Iakovos Tzanakis, Dmitry G. Eskin, Nicole Grobert, Adrian Mancuso, Richard Bean, Patrik Vagovic, Jiawei Mi. 2023-05-15. Ultrasound cavitation and exfoliation dynamics of 2D materials re-vealed in operando by X-ray free electron laser megahertz imaging. https://doi.org/10.1126/sciadv.ady9558

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