Emergent super-antiferromagnetic correlations in monolayers of Fe3O4 nanoparticles throughout the superparamagnetic blocking transition

Johnathon Rackham; Brittni Pratt; Dalton Griner; Dallin Smith; Yanping Cai; Roger G. Harrison; Alex Reid; Jeffrey Kortright; Mark K. Transtrum; Karine Chesnel

arXiv · 2306.11994

Emergent super-antiferromagnetic correlations in monolayers of Fe3O4 nanoparticles throughout the superparamagnetic blocking transition

Johnathon Rackham·Brittni Pratt·Dalton Griner·Dallin Smith·Yanping Cai·Roger G. Harrison·Alex Reid·Jeffrey Kortright·Mark K. Transtrum·Karine Chesnel

View original source ↗Read source document ↗Export metadata ↓

Abstract

We report nanoscale inter-particle magnetic orderings in self-assemblies of Fe3O4 nanoparticles (NPs), and the emergence of inter-particle antiferromagnetic (AF) (super-antiferromagnetic) correlations near the coercive field at low temperature. The magnetic ordering is probed via x-ray resonant magnetic scattering (XRMS), with the x-ray energy tuned to the Fe-L3 edge and using circular polarized light. By exploiting dichroic effects, a magnetic scattering signal is isolated from the charge scattering signal. The magnetic signal informs about nanoscale spatial orderings at various stages throughout the magnetization process and at various temperatures throughout the superparamagnetic blocking transition, for two different sizes of NPs, 5 and 11 nm, with blocking temperatures TB of 28 K and 170 K, respectively. At 300 K, while the magnetometry data essentially shows superparamagnetism and absence of hysteresis for both particle sizes, the XRMS data reveals the presence of non-zero (up to 9/100) inter-particle AF couplings when the applied field is released to zero for the 11 nm NPs. These AF couplings are drastically amplified when the NPs are cooled down below TB and reach up to 12/100 for the 5 nm NPs and 48/100 for the 11 nm NPs, near the coercive point. The data suggests that the particle size affects the prevalence of the AF couplings: compared to ferromagnetic (F) couplings, the relative prevalence of AF couplings at the coercive point increases from a factor ~ 1.6 to 3.8 when the NP size increases from 5 to 11 nm.

Explore related subjects

cond-mat.mes-hall cond-mat.mtrl-sci

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Johnathon Rackham, Brittni Pratt, Dalton Griner, Dallin Smith, Yanping Cai, Roger G. Harrison, Alex Reid, Jeffrey Kortright, Mark K. Transtrum, Karine Chesnel. 2023-06-21. Emergent super-antiferromagnetic correlations in monolayers of Fe3O4 nanoparticles throughout the superparamagnetic blocking transition. https://arxiv.org/abs/2306.11994

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Inverse Purcell Suppression of Decoherence in Majorana Qubits via Environmental Engineering

We show that the electromagnetic or phononic environment of a topological quantum device can be engineered to actively suppress decoherence. For a Majorana qubit in a superconducting wire, the exponentially small splitting $ε\sim e^{-L/ξ}$ that provides topological protection also makes the qubit vulnerable to low-frequency noise. From a microscopic local interaction, we derive the effective low-energy coupling between the Majorana parity operator and a bosonic field; the coupling strength itself is proportional to $ε$, reflecting the qubit's non-local nature. The resulting pure-dephasing rate scales as $Γ_ϕ\propto ε^2 S(ε)$, with $S(ε)$ the environmental noise power at frequency $ε$. In the experimentally relevant high-temperature regime ($k_B T \gtrsim \hbarε$), this gives $Γ_ϕ\propto ερ(ε) T$, where $ρ(ε)$ is the environmental density of states. By engineering an environment with a suppressed low-frequency density of states, $ρ_{\text{eng}}(ω) = ρ_0 (ω/ω_c)^α$ for $ω< ω_c$ ($α> 0$), the dephasing rate drops to $Γ_ϕ^{\text{eng}} \propto ε^{α+1} \propto e^{-(α+1)L/ξ}$. Thus, longer wires yield exponentially better coherence---a direct synergy with topological protection. This "inverse Purcell" effect, which suppresses the density of states at the qubit frequency, provides a quantitative design principle for environmental engineering. Our work establishes spectral density shaping as a practical method for enhancing coherence in topological quantum devices.

cond-mat.mes-hall↗

arXiv2026

Axionic tunneling from a topological Kondo insulator

Discoveries over the past two decades have revealed the remarkable ability of quantum materials to emulate relativistic properties of the vacuum, from Dirac cones in graphene to Dirac surface states of topological insulators. Yet one of the most elusive consequences of topology in quantum matter -- the axionic ${\bf E}\cdot{\bf B}$ contribution to the electromagnetic response, predicted to produce strong magnetoelectric effects -- remains experimentally challenging to detect. Here we report evidence for an axion-like magnetoelectric response obtained through scanning tunneling microscopy (STM) using a SmB$_6$ nanowire tip on an antiferromagnetic Fe$_{1+x}$Te sample. Our measurements reveal a striking voltage-induced magnetization: millivolt biases generate measurable tip magnetizations that reverse with the voltage. The magnitude, tunability, and reversibility of this signal are consistent with an axion-like ${\bf E} \cdot {\bf B}$ coupling, which naturally accounts for the voltage-odd magnetic component of the tip spectral function while strongly constraining a conventional static-magnetism interpretation. Moreover, millivolt-scale control of spin polarization in a tunnel junction provides a new route for probing axionic electrodynamics and opens avenues for future STM and spintronic applications.

cond-mat.mes-hall↗

arXiv2026

Exciton-mediated optical control of liquid-solid friction

Interfacial friction in nanofluidic systems can arise from fluctuation-induced coupling between liquid charge fluctuations and the internal excitations of the confining solid. Here, we develop a microscopic theory of exciton-mediated solid-liquid friction based on the coupling between optically generated excitons and charge fluctuations in water. We distinguish between static excitons, localized by disorder or functionalization, and dynamic excitons, which interact with water through polarization fluctuations. In both cases, we derive analytical formulas for the excitonic friction, which is experimentally tunable and can significantly reduce the slip length and thereby the hydraulic permeability of nanochannels. Applying our framework to carbon nanotubes, we quantitatively reproduce the recent measurements of Kistwal et al., showing a reduction of nanotube diffusion under optical excitation, without fitting parameters. More broadly, our results establish excitons as a mechanism to optically control nanofluidic transport and suggest that excitonic photoluminescence could provide an optical probe of flow velocity inside nanochannels.

cond-mat.mes-hall↗