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arXiv · 2307.06818

Tailoring the ferromagnetic surface potential landscape by a templating two-dimensional metal-organic porous network

Lu Lyu·Martin Anstett·Ka Man Yu·Azadeh Kadkhodazadeh·Martin Aeschlimann·Benjamin Stadtmüller
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Abstract

Two-dimensional metal-organic porous networks (2D-MOPNs) have been identified as versatile nanoarchitectures to tailor surface electronic and magnetic properties on noble metals. In this context, we propose a protocol to redecorate a ferromagnetic surface potential landscape using a 2D-MOPN. Ultrathin cobalt (Co) films grown on Au(111) exhibit a well-ordered surface triangular reconstruction. On the ferromagnetic surface, the adsorbed 2,4,6-tris(4-pyridyl)-1,3,5triazine (T4PT) molecules can coordinate with the native Co atoms to form a large-scale Co-T4PT porous network. The Co-T4PT network with periodic nanocavities serves as a templating layer to reshape the ferromagnetic surface potential. The subsequently deposited C60 molecules are steered by the network porous potential and the neighboring C60 interactions. The prototype of the ferromagnetic-supported 2D-MOPN is a promising template for the tailoring of molecular electronic and spin properties.

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Lu Lyu, Martin Anstett, Ka Man Yu, Azadeh Kadkhodazadeh, Martin Aeschlimann, Benjamin Stadtmüller. 2023-07-13. Tailoring the ferromagnetic surface potential landscape by a templating two-dimensional metal-organic porous network. https://arxiv.org/abs/2307.06818

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