Transverse spin selectivity in helical nanofibers prepared without any chiral molecule

Abstract

In the last decade, chirality-induced spin selectivity (CISS) has been attracting extensive interest. However, there still exists a large gap between experiments and quantitative theoretical results, and the microscopic mechanism of CISS, especially transverse CISS where electrons are injected perpendicular to the helix axis of chiral molecules, remains elusive. Here, we address these issues by performing a combined experimental and theoretical study on conducting polyaniline helical nanofibers which are synthesized in the absence of any chiral species. Large spin polarization is measured in both left- and right-handed nanofibers for electrons injected perpendicular to their helix axis, which is comparable to the value of parallel electron injection in other chiral molecules, and it will be reversed by switching the handedness between two enantiomers. We develop a theoretical model with extremely weak spin-orbit coupling arising exclusively from electron propagation between neighboring polyanilines and the numerical results are quantitatively consistent with the experimental data. Our results demonstrate that the supramolecular handedness is sufficient for spin-selective electron transmission in chiral molecules assembled from achiral monomers and the mechanism of transverse CISS is revealed.