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arXiv · 2407.19952

Viscous liquid dynamics modeled as random walks within overlapping hyperspheres

Mark F. B. Railton·Eva Uhre·Jeppe C. Dyre·Thomas B. Schrøder
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Abstract

The hypersphere model is a simple one-parameter model of the potential energy landscape of viscous liquids, which is defined as a percolating system of same-radius hyperspheres randomly distributed in $\mathbb{R}^{3N}$ in which $N$ is the number of particles. We study random walks within overlapping hyperspheres in 12 to 45 dimensions, i.e., above the percolation threshold, utilizing an algorithm for on-the-fly placement of the hyperspheres in conjunction with the kinetic Monte Carlo method. We find behavior typical of viscous liquids; thus decreasing the hypersphere density (corresponding to decreasing the temperature) leads to a slowing down of the dynamics by many orders of magnitude. The shape of the mean-square displacement as a function of time is found to be similar to that of the Kob-Andersen binary Lennard-Jones mixture and the Random Barrier Model, which predicts well the frequency-dependent fluidity of nine glass-forming liquids of different chemistry [Bierwirth et al., Phys. Rev. Lett. $\mathbf{119}, 248001\,(2017)$].

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Mark F. B. Railton, Eva Uhre, Jeppe C. Dyre, Thomas B. Schrøder. 2024-07-29. Viscous liquid dynamics modeled as random walks within overlapping hyperspheres. https://doi.org/10.1103/physreve.111.055301

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