Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 2411.17466

Magnetic polaronic exciton in A-type 2D van der Waals bulk material CrSBr

Xiaodong Shen·Jiajun Cao·Weizheng Liang·Borong Cong·Bao Ke·Jialong Zhao·Bingsuo Zou
View original source ↗Read source document ↗Export metadata ↓

Abstract

2D magnetic semiconductor CrSBr exhibits unique magneto-optical properties, yet its electronic structure and photophysical mechanisms remain unclear at high magnetic field and low temperature. Through comprehensive spectroscopic investigations, its charge-transfer band edge is identified at 500 nm. Below this band-edge, local excitonic magnetic polaronic states from Cr3+ ions out of FM aggregates in layer and bilayer could be seen due to phonon-spin-exciton coupling, in which magnetic polaronic PL1 emission occurs at 720 nm from single Cr3+ d-d transition, a dark-state pair exciton occurs at 850 nm in 10 K magnetic field, and double-peak PL2 emission at 920 nm out of Cr3+ FM trimer in monolayer is seen; besides, the magnetic bi-polaronic PL3 at 990 nm can be assigned to Cr3+ tetramers between FM adjacent layers. In magnetic field perpendicular to the layer, direct competition between PL1and dark-state excitons and PL2 and PL3 excitonic states persist in different temperatures. This study sheds light on the complicated magneto-exciton interactions in the multi-body effect of CrSBr, beneficial for quantum modulation in layered magnetic semiconductors.

Explore related subjects

cond-mat.mtrl-scicond-mat.mes-hallphysics.app-ph

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Xiaodong Shen, Jiajun Cao, Weizheng Liang, Borong Cong, Bao Ke, Jialong Zhao, Bingsuo Zou. 2024-11-26. Magnetic polaronic exciton in A-type 2D van der Waals bulk material CrSBr. https://arxiv.org/abs/2411.17466

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Incommensurate structural and magnetic modulations in potassium-rich cryptomelane, K$_x$Mn$_8$O$_{16}$ ($x\approx1.45$)

Cryptomelane is a hollandite-like material consisting of K$^+$ cations in an $α$-MnO$_2$ tunnel-like crystallographic motif. Cryptomelane with stoichiometry K$_x$Mn$_8$O$_{16}$ ($x\approx1.45$) has been synthesized and its magnetic properties investigated using variable-temperature magnetic susceptibility, heat capacity, and neutron powder diffraction. Three distinct transitions at $T_1=184$\,K, $T_2=54.5$\,K, and $T_3=24$\,K are observed. At $T_1$ there is a subtle tetragonal$\rightarrow$monoclinic transition associated with emergence of a set of non-magnetic superstructure peaks indexable to a $\vec{k}_\mathrm{struc}\approx0.74\vec{c^*}$ incommensurate modulation parallel to the $α$-MnO$_2$ tunnels. Our findings are consistent with a relation previously reported in titanate hollandites, that $x\approx2|\vec{k}_\mathrm{struc}|$. Magnetic Bragg peaks emerge below $T_2=54.5$\,K, and their positions indicate an incommensurate modulated magnetic structure. The model consistent with the data is a dual-$\vec{k}_\mathrm{mag}$ structure with a ferromagnetic $|\vec{k}_\mathrm{mag}|=0$ component and an incommensurate $\vec{k}_\mathrm{mag}\approx0.37\vec{c^*}$, with the latter most likely to be helical. The period of oscillation of the incommensurate magnetic component is in line with predictions based on a Heisenberg spin Hamiltonian [Mandal \textit{et al}. Phys. Rev. B 90, 104420 (2014)]. Below $T_3=24$\,K, there is a magnetic transition, which gives rise to a different set of magnetic Bragg peaks indicative of a highly complex magnetic structure.

cond-mat.mtrl-sci↗
arXiv2026

An anisotropic functional for two-dimensional material systems

Density function theory is the workhorse of modern electronic structure theory. However, its accuracy in practical calculations is limited by the choice of the exchange-correlation potential. In this respect, two-dimensional materials pose a special challenge, as all these materials and their heterostructures have a crucial similarity. The underlying atomic structures are strongly spatially inhomogeneous, implying that current exchange-correlation functionals, that in almost all cases are isotropic, are ill-prepared for an accurate description. We present an anisotropic screened-exchange potential, that remedies this problem and reproduces the band-gap of 2D materials as well as the piecewise linearity of the total energy with fractional occupation number.

cond-mat.mtrl-sci↗
arXiv2026

Thermally-driven reorientation of the Néel vector in altermagnetic MnTe

Altermagnets are novel magnetic systems that possess a spin-polarized electronic band structure without a net magnetic moment, making them promising for device applications. Hexagonal MnTe, a prototypical altermagnet, arguably exhibits the most properties consistent with theoretical predictions, including an anomalous Hall effect despite a vanishing net magnetization, and altermagnetinduced electronic band splitting. However, fundamental questions remain, including why some effects only appear significantly below the magnetic ordering temperature. Here, we resolve this discrepancy by revealing a reorientation of the Néel vector in single-crystalline MnTe. The Néel vector points 30° from the a-axis at low $T$, before aligning directly with the a-axis around $T\simeq 260$ K. We attribute this to single-ion anisotropy, which depends on temperature-dependent lattice parameters. We obtained these results using muon-spin spectroscopy, magnetization measurements, and X-ray diffraction; we show that the findings are consistent with neutron diffraction. Manipulating this effect, for example through strain, could unlock sensitive electronic detection schemes for external stimuli, paving the way for functional altermagnetic devices.

cond-mat.mtrl-sci↗