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arXiv · 2412.20384

Chemical Compositions of Soot Samples in Gold Electrode Capacitors: Molecular Simulations

Vitaly V. Chaban·Nadezhda A. Andreeva
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Abstract

Electrical breakdown in a dielectric capacitor occurs when the electric field strength across the dielectric material exceeds its breakdown strength. A conductive channel through the dielectric emerges, resulting in a sudden surge of current. Self-healing represents a phenomenon of restoration of a capacitor's performance. The efficiency of self-healing depends on the products of high-temperature decomposition of the electrode and dielectric. We report atomistic simulations of the soot's chemical composition in the case of gold electrodes and four popular dielectric polymers: polypropylene (PP), polyethylene terephthalate (PET), polycarbonate (PC), and polyimide (PI). We unravel that gold atoms form clusters within the carbon-rich soot, limiting their interactions with non-metal elements. The oxygen atoms of PET, PC, and PI act as stabilizers of gold thanks to electrostatic attraction. Compared to zinc, gold equalizes the soot conductivity in all samples but does not impact polymer gasification. The suitability of dielectrics for self-healing must be rated based on the volatile by-products: PP > PC > PET > PI. Mind that PP issues three times more gases than PI. Therefore, the size of semiconducting soot is substantially smaller in the case of PP than in the case of PI. The obtained numerical results provide unprecedented physical insights into the phenomenon of self-healing and clearly drive the efforts to extend the lifespans of the metalized film capacitors.

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Vitaly V. Chaban, Nadezhda A. Andreeva. 2024-12-29. Chemical Compositions of Soot Samples in Gold Electrode Capacitors: Molecular Simulations. https://arxiv.org/abs/2412.20384

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