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arXiv · 2503.20843

Mobility of single vacancies and adatoms in graphene at room temperature

Tuan T. Tran·Per O. Å. Persson·Ngan Pham·Radek Holenak·Daniel Primetzhofer
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Abstract

We investigate the mobility of structural defects, adatoms, and defect-adatom combinations in self-supporting graphene subjected to keV ion irradiation. In the first scenario, homogeneous irradiation using 20 keV Ar$^+$ ions at a dose of $3 \times 10^{14}$ ions/cm$^2$ induces tensile strain of up to 0.8\%. This strain diminishes with increasing defect density at the dose of $5 \times 10^{14}$ ions/cm$^2$, indicating a strain-relaxation mechanism. Contrary to the expected localized behavior, vacancies exhibit long-range interactions, contributing to global strain effects across the lattice. In the second scenario, by employing a nanopore mask, we spatially confined defect generation to periodically aligned circular regions surrounded by non-irradiated material, enabling direct observation of vacancy and adatom dynamics. Selected area electron diffraction (SAED) reveals significant structural damage in areas adjacent to the irradiated regions, suggesting that single vacancies migrate over distances on the order of 100 nm from irradiated to non-irradiated zones even at room temperature. The build-up of lattice strain observed in this study may play a key role in lowering the migration barrier of single vacancies, thereby facilitating their diffusion into pristine lattice regions. Furthermore, the findings highlight the role of pre-existing surface contaminants in preserving lattice integrity through a self-healing mechanism, where adatom-induced lattice reconstruction mitigates defect-induced structural degradation.

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Tuan T. Tran, Per O. Å. Persson, Ngan Pham, Radek Holenak, Daniel Primetzhofer. 2025-03-26. Mobility of single vacancies and adatoms in graphene at room temperature. https://arxiv.org/abs/2503.20843

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