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arXiv · 2511.00201

Constructing a bifunctional platform based on Mn2+-doped Mg2Y8(SiO4)6O2 phosphors for multi-parameter optical thermometry and manometry

Zhiyu Pei·Shuailing Ma·Maja Szymczak·Lukasz Marciniak·Tian Cui·Laihui Luo·Peng Du
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Abstract

Series of the Mn2+-doped Mg2Y8(SiO4)6O2 phosphors were synthesized. Upon excitation at 408 nm, these phosphors exhibited intense orange emission originating from Mn2+, with concentration quenching observed beyond x = 0.07, and they also demonstrated excellent thermal stability. For optical thermometry, two independent parameters, emission band centroid (λ) and lifetime, were employed as thermal indicators, yielding sensitivities of dλ/dT = 0.053 nm K-1 and SR = 0.86% K-1, respectively. High-pressure in-situ X-ray diffraction revealed that the phosphors retained structural integrity under compression, accompanied by a progressive lattice contraction. With increasing pressure (0.13-10.89 GPa), a spectral red-shift was observed, corresponding to a pressure sensitivity of dλ/dp = 4.75 nm GPa-1. Additionally, pressure-dependent shifts in color coordinates allowed the development of a colorimetric manometric response, achieving a relative sensitivity of 3.27% GPa-1. Remarkably, the pressure-induced spectral shift of Mn2+ emission, characterized by low thermal cross-sensitivity, enabled a highly reliable ratiometric manometric strategy, with a relative sensitivity of 72% GPa-1. Notably, the system delivered the highest TIMF reported to date above 3 GPa, peaking at 1940 K GPa-1 at 7 GPa. These results position Mn2+-doped Mg2Y8(SiO4)6O2 phosphors as a highly promising bifunctional material for next-generation, multi-parameter optical sensing applications under extreme conditions.

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Zhiyu Pei, Shuailing Ma, Maja Szymczak, Lukasz Marciniak, Tian Cui, Laihui Luo, Peng Du. 2025-10-31. Constructing a bifunctional platform based on Mn2+-doped Mg2Y8(SiO4)6O2 phosphors for multi-parameter optical thermometry and manometry. https://arxiv.org/abs/2511.00201

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