Sonochemically Boosted Hydrogen Evolution Activity of Janus TMD Monolayers

Abstract

2D electrocatalysts that enable hydrogen evolution at low overpotentials offer an attractive alternative to expensive platinum-based systems. Here, we report the growth of Janus transition metal dichalcogenide (TMD) monolayers (MLs), SeMoS and SeWS, on Au foils using chemical vapor deposition, and systematically compare their catalytic properties in the context of hydrogen evolution reaction (HER) with those of their parent TMDs. The Janus MLs exhibited significantly enhanced catalytic performance relative to the parent TMDs. Furthermore, these MLs on Au foils were subjected to sonochemical treatment in polar and non-polar solvents, in which the treatment with polar solvents led to a substantial improvement in the HER activity of Janus MLs. In particular, SeMoS MLs treated with water showed a low overpotential of ~63 mV, a Tafel slope of ~42 mV/dec, and an exchange current density of ~10$^{-3}$ mA cm$^{- 2}$, approaching that of platinum. Analyses indicate that enhanced electrocatalytic activity is associated with tensile strain induced by Au surface restructuring and the formation of defects in Janus MLs, as shown by experimental observations and by density functional theory calculations. The enhancement in catalytic performance due to sonochemical treatment emphasizes the importance of our results for developing novel catalytic systems for HER based on Janus 2D materials.