Bridging the continuum and the kinetic-Boltzmann theories of heat flow through generalized Knudsen numbers

Abstract

Heat conduction in semiconductor crystals is fundamentally governed by the linearized Peierls-Boltzmann equation (LPBE) for phonon transport, that arises out of a kinetic theory for phonon quasiparticles. Yet, continuum theories such as the Fourier's heat diffusion, weakly quasiballistic and hydrodynamic heat equations are often used to explain the experimental observations of heat flow in these materials. Here, we show that a systematic reduction of the LPBE into such equivalent continuum descriptions are possible only for the limiting values of a set of generalized Knudsen numbers. We further show that all of these continuum heat flow regimes, along with the ballistic heat flow, can be described by a single continuum equation for the temperature field that originates from the eigenmode analysis of the LPBE, thus offering a unified picture of all possible heat flow regimes in semiconducting crystals. Using quantitative examples on twenty three technologically important semiconductors, we show that several previously-unidentified features of the non-Fourier heat flow regimes emerge from this generalized Knudsen number framework such as (1) the mutual exclusivity of the weakly quasiballistic and the hydrodynamic heat flow regimes, (2) length-dependent velocity of the hydrodynamic second sound temperature wave and a characteristic heating length for the strongest hydrodynamic second sound, (3) characteristic frequency-domain temperature response distinguishing the hydrodynamic second sound from the ballistic heat flow regime and, (4) a new non-oscillatory signature of transient hydrodynamic heat flow. Our work formally bridges the continuum and the particulate descriptions of heat flow, and provides insights into the important signatures of temperature dynamics in each of these heat flow regimes, that will aid in their unambiguous experimental observations in the future.