Photoconductive nonpolar liquids based on azobenzene

Abstract

The weakly conductive properties of mixtures of organic surfactants in nonpolar liquids are fundamental to many electrohydrodynamic phenomena and underpin several cutting-edge technologies, particularly the development of electrophoretic displays. To date, tuning the electrical properties of these systems has involved modifying their composition, including surfactant type and concentration, water content, and the carrier liquid, all of which influence their behavior. Here, we use photoresponsive molecules to control electric phenomena in nonpolar liquids externally with light irradiation, thereby rendering them photoconductive. In particular, we examine azobenzene solutions in toluene, whose conductivity can be adjusted by two colors of light: UV induces trans to cis isomerization, leading to an increase in conductivity, while blue light triggers cis to trans back-isomerization, decreasing conductivity. The findings of this study suggest new ways to expand the applications of weakly conductive organic fluids, such as in self-regulating devices that respond to sunlight or in externally programmable displays.