Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · cond-mat/0509108

Magnetic behavior of EuCu2As2: Delicate balance between antiferromagnetic and ferromagnetic order

Kausik Sengupta·P. L. Paulose·E. V. Sampathkumaran·Th. Doert·J. P. F. Jemetio
View original source ↗Read source document ↗Export metadata ↓

Abstract

The Eu-based compound, EuCu2As2, crystallizing in the ThCr2Si2-type tetragonal structure, has been synthesized and its magnetic behavior has been investigated by magnetization (M), heat-capacity (C) and electrical resistivity (rho) measurements as a function of temperature (T) and magnetic field (H) as well as by 151Eu Moessbauer measurements. The results reveal that Eu is divalent ordering antiferromagnetically below 15 K in the absence of magnetic field, apparently with the formation of magnetic Brillouin-zone boundary gaps. A fascinating observation is made in a narrow temperature range before antiferromagnetism sets in: That is, there is a remarkable upturn just below 20 K in the plot of magnetic susceptibility versus T even at low fields, as though the compound actually tends to order ferromagnetically. There are corresponding anomalies in the magnetocaloric effect data as well. In addition, a small application of magnetic field (around 1 kOe at 1.8 K) in the antiferromagnetic state causes spin-reorientation effect. These results suggest that there is a close balance between antiferromagnetism and ferromagnetism in this compound

Explore related subjects

cond-mat.str-elcond-mat.mtrl-sci

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Kausik Sengupta, P. L. Paulose, E. V. Sampathkumaran, Th. Doert, J. P. F. Jemetio. 2005-09-05. Magnetic behavior of EuCu2As2: Delicate balance between antiferromagnetic and ferromagnetic order. https://doi.org/10.1103/physrevb.72.184424

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Real-space determination of orbital states driving successive phase transitions in FeV2O4

Direct experimental access to orbital states in strongly correlated materials remains a major challenge, despite their central role in driving coupled structural and magnetic phase transitions. In systems where electronic correlations, electron-lattice coupling, and relativistic spin-orbit interactions compete on comparable energy scales, even first-principles calculations often yield multiple metastable solutions, hindering the unambiguous identification of the ground state. Here, we demonstrate that the orbital states of the spinel oxide FeV2O4, which possesses active orbital degrees of freedom on both Fe and V ions, are uniquely resolved by combining valence electron density (VED) analysis based on state-of-the-art synchrotron x-ray diffraction with spin-polarized density-functional-theory calculations. Our results reveal that temperature-dependent rearrangements of orbital occupations drive successive structural transitions that accompany collinear and noncoplanar ferrimagnetic orders, establishing a direct correspondence between orbital anisotropy and spin structure. More broadly, this work shows that experimentally determined VED provides a decisive real-space constraint on competing theoretical solutions, offering a powerful and broadly applicable framework for elucidating the microscopic mechanisms of complex phase transitions in strongly correlated electron systems.

cond-mat.str-el↗
arXiv2026

Macroscopic Zero-Mode Manifold Isolated by Quantum Chaos

Chaotic many-body spectra are expected to densely fill their energy window. We show that constrained spin chains with chiral symmetry evade this expectation by hosting an exponentially large manifold of symmetry-protected exact zero modes separated from the surrounding spectrum by a sharp gap at zero energy. The gap is generated by chaotic level repulsion, with width set by the number of zero modes times the mean level spacing. We verify this mechanism in an East-West kinetically constrained chain, develop a minimal random-matrix description, and show how the gap can be detected through linear-response spectroscopy.

cond-mat.str-el↗
arXiv2026

Textures as a phase-transition probe for quantum spin chains

The idea of quantum texture has been recently proposed and used as a tool for quantifying coherences and for quantum gate identification. In this work we offer a study on its usage to quantum phase transitions, demonstrating the rugosity metric as a simple tool for effective phase-transition probing. We establish the link between rugosity in the computational basis and the hierarchy of spin correlators, and analyze rugosities defined in the global ground-state and in ground-states belonging to different magnetization sectors (to which we refer to as global vs symmetry-resolved rugosities) to study the phase diagram of the Heisenberg XXZ model. We find distinct rugosity signatures at both transition points. In particular, a sharp feature appears at $Δ=1$ already for small systems, revealing a pronounced sensitivity of the correlation hierarchy encoded by the texture to this point. Since the BKT transition coincides with the isotropic $SU(2)$ point of the XXZ model, this behavior may reflect a particular sensitivity of rugosity to the structure of the spin-correlation hierarchy at isotropy.

cond-mat.str-el↗