arXiv subjects

Benjamin Fortman

Publications and source records attributed to Benjamin Fortman.

5 recordsLinked to original sources

arXiv2023

Demonstration of NV-detected $^{13}$C NMR at 4.2 T

The nitrogen-vacancy (NV) center in diamond has enabled studies of nanoscale nuclear magnetic resonance (NMR) and electron paramagnetic resonance with high sensitivity in small sample volumes. Most NV-detected NMR (NV-NMR) experiments are performed at low magnetic fields. While low fields are useful in many applications, high-field NV-NMR with fine spectral resolution, high signal sensitivity, and the capability to observe a wider range of nuclei is advantageous for surface detection, microfluidic, and condensed matter studies aimed at probing micro- and nanoscale features. However, only a handful of experiments above 1 T were reported. Herein, we report $^{13}$C NV-NMR spectroscopy at 4.2 T, where the NV Larmor frequency is 115 GHz. Using an electron-nuclear double resonance technique, we successfully detect NV-NMR of two diamond samples. The analysis of the NMR linewidth based on the dipolar broadening theory of Van Vleck shows that the observed linewidths from sample 1 are consistent with the intrinsic NMR linewidth of the sample. For sample 2 we find a narrower linewidth of 44 ppm. This work paves the way for new applications of nanoscale NV-NMR.

cond-mat.mes-hall↗

arXiv2021

Electron-electron double resonance detected NMR spectroscopy using ensemble NV centers at 230 GHz and 8.3 Tesla

The nitrogen-vacancy (NV) center has enabled widespread study of nanoscale nuclear magnetic resonance (NMR) spectroscopy at low magnetic fields. NMR spectroscopy at high magnetic fields significantly improves the technique's spectral resolution, enabling clear identification of closely related chemical species. However, NV-detected NMR is typically performed using AC sensing through electron spin echo envelope modulation (ESEEM), a hyperfine spectroscopic technique that is not feasible at high magnetic fields. Within this paper, we have explored an NV-detected NMR technique for applications of high field NMR. We have demonstrated optically detected magnetic resonance (ODMR) with the NV Larmor frequency of 230 GHz at 8.3 Tesla, corresponding to a proton NMR frequency of 350 MHz. We also demonstrated the first measurement of electron-electron double resonance detected NMR (EDNMR) using the NV center and successfully detected $^{13}C$ nuclear bath spins. The described technique is limited by the longitudinal relaxation time ($T_1$), not the transverse relaxation time ($T_2$). Future applications of the method to perform nanoscale NMR of external spins at 8.3 T and even higher magnetic fields are also discussed.

cond-mat.mes-hall↗

arXiv2020

Demonstration of NV-detected ESR spectroscopy at 115 GHz and 4.2 Tesla

High frequency electron spin resonance (ESR) spectroscopy is an invaluable tool for identification and characterization of spin systems. Nanoscale ESR using the nitrogen-vacancy (NV) center has been demonstrated down to the level of a single spin. However, NV-detected ESR has exclusively been studied at low magnetic fields, where spectral overlap prevents clear identification of spectral features. Within this work, we demonstrate NV-detected ESR measurements of single-substitutional nitrogen impurities in diamond at a NV Larmor frequency of 115 GHz and the corresponding magnetic field of 4.2 Tesla. The NV-ESR measurements utilize a double electron-electron resonance sequence and are performed using both ensemble and single NV spin systems. In the single NV experiment, chirp pulses are used to improve the population transfer and for NV-ESR measurements. This work provides the basis for NV-based ESR measurements of external spins at high magnetic fields.

cond-mat.mes-hall↗

arXiv2019

Understanding the Linewidth of the ESR Spectrum Detected by a Single NV Center in Diamond

Spectral analysis of electron spin resonance (ESR) is a powerful technique for various investigations including characterization of spin systems, measurements of spin concentration, and probing spin dynamics. The nitrogen-vacancy (NV) center in diamond is a promising magnetic sensor enabling improvement of ESR sensitivity to the level of a single spin. Therefore, understanding the nature of NV-detected ESR (NV-ESR) spectrum is critical for applications to nanoscale ESR. Within this work we investigate the linewidth of NV-ESR from single substitutional nitrogen centers (called P1 centers). NV-ESR is detected by a double electron-electron resonance (DEER) technique. By studying the dependence of the DEER excitation bandwidth on NV-ESR linewidth, we find that the spectral resolution is improved significantly and eventually limited by inhomogeneous broadening of the detected P1 ESR. Moreover, we show that the NV-ESR linewidth can be as narrow as 0.3 MHz.

cond-mat.mes-hall↗

arXiv2018

Demonstration of fidelity improvement using dynamical decoupling with superconducting qubits

Quantum computers must be able to function in the presence of decoherence. The simplest strategy for decoherence reduction is dynamical decoupling (DD), which requires no encoding overhead and works by converting quantum gates into decoupling pulses. Here, using the IBM and Rigetti platforms, we demonstrate that the DD method is suitable for implementation in today's relatively noisy and small-scale cloud based quantum computers. Using DD, we achieve substantial fidelity gains relative to unprotected, free evolution of individual superconducting transmon qubits. To a lesser degree, DD is also capable of protecting entangled two-qubit states. We show that dephasing and spontaneous emission errors are dominant in these systems, and that different DD sequences are capable of mitigating both effects. Unlike previous work demonstrating the use of quantum error correcting codes on the same platforms, we make no use of post-selection and hence report unconditional fidelity improvements against natural decoherence.

quant-ph↗