arXiv subjects

Junjie Li

Publications and source records attributed to Junjie Li.

At least 163 records · Page 9Linked to original sources

arXiv2021

Crossover from lamellar to spongy ice morphologies within a single ice crystal during unidirectional freezing of an aqueous solution

Ice growth from liquid phase has been extensively investigated in various conditions, especially for ice freely grown in undercooled water and aqueous solutions. Although unidirectional ice growth plays a significant role in sea ice and freeze casting, the detailed pattern formation of unidirectionally grown ice in an aqueous solution remains elusive. For the first time, we in situ proved a crossover from lamellar to spongy ice morphologies of a single ice crystal via unidirectional freezing of an aqueous solution. The spongy ice morphology originates from the intersect of tilted lamellar ice and is observed in a single ice crystal, which is intrinsically different from the competitive growth of bi-crystal composed of two differently orientated grains in directional solidification. These results provide a complete physical picture of unidirectionally grown ice from aqueous solution and are believed to promote our understanding of various pattern of ice in many relevant domains where pattern formation of ice crystal is vital.

cond-mat.mtrl-sci↗

arXiv2020

The planar interface instability during freezing of a polymer solution: Diffusion-controlled or not?

Freezing of polymer solutions has been extensively investigated from many aspects, especially the complex pattern formation. The cell/dendrite micro-structures are believed to be in the type of diffusion-induced M-S instability. However, the presence of polymer as an impurity in water is significantly different from that of small ions. The quantitative transient investigation on directional freezing of polymer solutions remains lack due to some challenges. For the first time, we observed the planar instability behaviors during unidirectional freezing of a polymer solution together with a typical ionic solution with manipulated ice orientation, and their pattern formation of S/L interface morphology as a function of time in the transient planar instability process has been revealed and compared to each other. It is found with real-time observation that the polymer solution exhibits a global instability mode instead of a local instability mode that is common in ionic solution during planar instability. W-L model was applied to quantitatively address the variation of solute recoil of ionic/polymer solution. And it is found that the W-L model can only reproduce the solute recoil of ionic solution instead of polymer solution, which indicates the complex physics behind freezing of a polymer solution. The paper provides a spectacular contrast of directional freezing process between polymer solution and ionic solution and is believed to promote relevant investigations in terms of the theoretical approach to describing the freezing behavior of polymer solution.

cond-mat.soft↗

arXiv2020

In situ visualization of tip undercooling and lamellar microstructure evolution of sea ice with manipulated orientation

Sea ice growth with lamellar microstructure containing brine channels has been extensively investigated. However, the quantitative growth information of sea ice remains lack due to the uncontrolled crystalline orientation in previous investigations. For the first time, we in-situ observed the unidirectional growth of lamellar sea ice with well-manipulated ice crystal orientation and visualized tip undercooling of sea ice. A semi-empirical model was proposed to quantitatively address the variation of tip undercooling with growth velocity and salinity and compared with a very recent analytical model. With the real-time observation, interesting phenomena of doublon tip in cellular ice growth and growth direction shift of ice dendritic tip were discovered for the first time, which are attributed to the complex solutal diffusion and anisotropic interface kinetics in sea ice growth. The quantitative experiment provides a clear micro scenario of sea ice growth, and will promote relevant investigations of sea ice in terms of the theoretical approach to describing the diffusion field around faceted ice dendritic tip.

cond-mat.mtrl-sci↗

arXiv2020

Single ice crystal growth with controlled orientation during directional freezing

Ice growth has attracted great attention for its capability of fabricating hierarchically porous microstructure. However, the formation of tilted lamellar microstructure during freezing needs to be reconsidered due to the limited control of ice orientation with respect to thermal gradient during in-situ observations, which can greatly enrich our insight into architectural control of porous biomaterials. This paper provides an in-situ study of solid/liquid interface morphology evolution of directionally solidified single crystal ice with its C-axis (optical axis) perpendicular to directions of both thermal gradient and incident light in poly (vinyl alcohol, PVA) solutions. Misty morphology and V-shaped lamellar morphology were clearly observed in-situ for the first time. Quantitative characterizations on lamellar spacing, tilt angle and tip undercooling of lamellar ice platelets provide a clearer insight into the inherent ice growth habit in polymeric aqueous systems and are suggested exert significant impact on future design and optimization in porous biomaterials.

cond-mat.mtrl-sci↗

arXiv2020

Probing the pathway of an ultrafast structural phase transition to illuminate the transition mechanism in Cu2S

Disentangling the primary order parameter from secondary order parameters in phase transitions is critical to the interpretation of the transition mechanisms in strongly correlated systems and quantum materials. Here we present a study of structural phase transition pathways in superionic Cu2S nanocrystals that exhibit intriguing properties. Utilizing ultrafast electron diffraction techniques sensitive in both momentum-space and the time-domain, we distinguish the dynamics of crystal symmetry breaking and lattice expansion in this system. We are able to follow the transient states along the transition pathway and so observe the dynamics of both the primary and secondary order parameters. Based on these observations we argue that the mechanism of the structural phase transition in Cu2S is dominated by the electron-phonon coupling. This mechanism advances the understanding from previous results where the focus was solely on dynamic observations of the lattice expansion.

cond-mat.str-el↗

arXiv2020

Rapid Determination of Antimicrobial Susceptibility by Stimulated Raman Scattering Imaging of D2O Metabolic Incorporation in a Single Bacterium

Rapid antimicrobial susceptibility testing (AST) is urgently needed for treating infections with correct antibiotics and slowing down the emergence of antibiotic-resistant bacteria. Here, we report a phenotypic platform that rapidly produces AST results by femtosecond stimulated Raman scattering imaging of deuterium oxide (D2O) metabolism. Metabolic incorporation of D2O into biomass in a single bacterium is probed in as short as 10 minutes after culture in 70% D2O medium, the fastest among current technologies. Single-cell metabolism inactivation concentration (SC-MIC) is obtained in less than 2.5 hours from colony to results. The SC-MIC results of 37 sets of samples, which include 8 major bacterial species and 14 different antibiotics often encountered in clinic, are validated by standard minimal inhibitory concentration blindly measured via broth microdilution. Towards clinical translation, SRS imaging of D2O metabolic incorporation and SC-MIC determination after 1-h antibiotics treatment and 30-minutes mixture of D2O and antibiotics incubation of bacteria in urine or whole blood is demonstrated.

physics.bio-ph↗

arXiv2020

Low-Latency and Fresh Content Provision in Information-Centric Vehicular Networks

In this paper, the content service provision of information-centric vehicular networks (ICVNs) is investigated from the aspect of mobile edge caching, considering the dynamic driving-related context information. To provide up-to-date information with low latency, two schemes are designed for cache update and content delivery at the roadside units (RSUs). The roadside unit centric (RSUC) scheme decouples cache update and content delivery through bandwidth splitting, where the cached content items are updated regularly in a round-robin manner. The request adaptive (ReA) scheme updates the cached content items upon user requests with certain probabilities. The performance of both proposed schemes are analyzed, whereby the average age of information (AoI) and service latency are derived in closed forms. Surprisingly, the AoI-latency trade-off does not always exist, and frequent cache update can degrade both performances. Thus, the RSUC and ReA schemes are further optimized to balance the AoI and latency. Extensive simulations are conducted on SUMO and OMNeT++ simulators, and the results show that the proposed schemes can reduce service latency by up to 80\% while guaranteeing content freshness in heavily loaded ICVNs.

cs.NI↗

arXiv2020

Suphx: Mastering Mahjong with Deep Reinforcement Learning

Artificial Intelligence (AI) has achieved great success in many domains, and game AI is widely regarded as its beachhead since the dawn of AI. In recent years, studies on game AI have gradually evolved from relatively simple environments (e.g., perfect-information games such as Go, chess, shogi or two-player imperfect-information games such as heads-up Texas hold'em) to more complex ones (e.g., multi-player imperfect-information games such as multi-player Texas hold'em and StartCraft II). Mahjong is a popular multi-player imperfect-information game worldwide but very challenging for AI research due to its complex playing/scoring rules and rich hidden information. We design an AI for Mahjong, named Suphx, based on deep reinforcement learning with some newly introduced techniques including global reward prediction, oracle guiding, and run-time policy adaptation. Suphx has demonstrated stronger performance than most top human players in terms of stable rank and is rated above 99.99% of all the officially ranked human players in the Tenhou platform. This is the first time that a computer program outperforms most top human players in Mahjong.

cs.AI↗

arXiv2020

A Study of Selectively Digital Etching Silicon-Germanium with Nitric and Hydrofluoric Acids

A digital etching method was proposed to achieve excellent control of etching depth. The digital etching characteristics of p+ Si and Si0.7Ge0.3 using the combinations of HNO3 oxidation and BOE oxide removal processes were studied. Experiments showed that oxidation saturates with time due to low activation energy. A physical model was presented to describe the wet oxidation process with nitric acid. The model was calibrated with experimental data and the oxidation saturation time, final oxide thickness, and selectivity between Si0.7Ge0.3 and p+ Si were obtained. The digital etch of laminated Si0.7Ge0.3/p+ Si was also investigated. The depth of the tunnels formed by etching SiGe layers between two Si layers was found in proportion to digital etching cycles. And oxidation would also saturate and the saturated relative etched amount per cycle (REPC) was 0.5 nm (4 monolayers). A corrected selectivity calculation formula was presented. The oxidation model was also calibrated with Si0.7Ge0.3/p+ Si stacks, and selectivity from model was the same with the corrected formula. The model can also be used to analyze process variations and repeatability. And it could act as a guidance for experiment design. Selectivity and repeatability should make a trade-off.

physics.app-ph↗

arXiv2020

Vector exceptional points with strong superchiral fields

Exceptional points(EPs), branch points of complex energy surfaces at which eigenvalues and eigenvectors coalesce, are ubiquitous in non-Hermitian systems. Many novel properties and applications have been proposed around the EPs. One of the important applications is to enhance the detection sensitivity. However, due to the lack of single-handed superchiral fields, all of the proposed EP-based sensing mechanisms are only useful for the non-chiral discrimination. Here, we propose theoretically and demonstrate experimentally a new type of EP, which is a called radiation vector EP, to fulfill the homogeneous superchiral fields for chiral sensing. This type of EP is realized by suitably tuning the coupling strength and radiation losses for a pair of orthogonal polarization modes in the photonic crystal slab. Based on the unique modal-coupling property at the vector EP, we demonstrate that the uniform superchiral fields can be generated with two beams of lights illuminating on the photonic crystal slab from opposite directions. Thus, the designed photonic crystal slab, which supports the vector EP, can be used to perform surface-enhanced chiral detection. Our findings provide a new strategy for ultrasensitive characterization and quantification of molecular chirality, a key aspect for various bioscience and biomedicine applications.

physics.optics↗

arXiv2020

Concurrent probing of electron-lattice dephasing induced by photoexcitation in 1T-TaSeTe using ultrafast electron diffraction

It has been technically challenging to concurrently probe the electrons and the lattices in materials during non-equilibrium processes, allowing their correlations to be determined. Here, in a single set of ultrafast electron diffraction patterns taken on the charge-density-wave (CDW) material 1T-TaSeTe, we discover a temporal shift in the diffraction intensity measurements as a function of scattering angle. With the help of dynamic models and theoretical calculations, we show that the ultrafast electrons probe both the valence-electron and lattice dynamic processes, resulting in the temporal shift measurements. Our results demonstrate unambiguously that the CDW is not merely a result of the periodic lattice deformation ever-present in 1T-TaSeTe but has significant electronic origin. This method demonstrates a novel approach for studying many quantum effects that arise from electron-lattice dephasing in molecules and crystals for next-generation devices.

cond-mat.mtrl-sci↗

arXiv2019

Multiplex stimulated Raman scattering imaging cytometry reveals cancer metabolic signatures in a spatially, temporally, and spectrally resolved manner

In situ measurement of cellular metabolites is still a challenge in biology. Conventional methods, such as mass spectrometry or fluorescence microscopy, would either destruct the sample or introduce strong perturbations to the functions of target molecules. Here, we present multiplex stimulated Raman scattering (SRS) imaging cytometry as a label-free single-cell analysis platform with chemical specifity, and high-throughput capabilities. Cellular compartments such as lipid droplets, endoplasmic reticulum, and nuclei are seperated from the cytoplasm. Based on these chemical segmentations, 260 features from both morphology and molecular composition were generated and analyzed for each cell. Using SRS imaging cytometry, we studied the metabolic responses of human pancreatic cancer cells under stress by starvation and chemotherapy drug treatments. We unveiled lipid-facilitated protrusion as a metabolic marker for stress-resistant cancer cells through statistical analysis of thousands of cells. Our findings also demonstrate the potential of targeting lipid metabolism for selective treatment of starvation-resistant and chemotherapy-resistant cancers. These results highlight our SRS imaging cytometry as a powerful label-free tool for biological discoveries with a high-throughput, high-content capacity.

q-bio.QM↗

arXiv2019

Selective Diffraction with Complex Amplitude Modulation by Dielectric Metasurfaces

Metasurfaces have attracted extensive interests due to their ability to locally manipulate optical parameters of light and easy integration to complex optical systems. Particularly, metasurfaces can provide a novel platform for splitting and diffracting light into several beams with desired profile, which is in contrast to traditional gratings. Here, we propose and experimentally demonstrate a novel method for generating independently selective diffraction orders. Our method is based on complex amplitude modulation with ultrathin dielectric metasurfaces. By tailoring the geometric parameters of silicon nanofin structures, we can spatially control the geometric and dynamic phase as well as the amplitude simultaneously. We compare the results with a metasurface that uses a phase-only modulation, to verify such selective diffraction can be solely efficiently achieved with complex amplitude modulation. Besides, the diffraction angles of each order have been measured, which are consistent with standard grating theory. Our developed method for achieving selective diffraction with metasurfaces has potential applications in beam shaping, parallel laser fabrication, and nanoscale optical detection.

physics.optics↗

arXiv2019

Nanoscale polarization manipulation and encryption based on dielectric metasurfaces

Manipulating the polarization of light is highly desired for versatile applications ranging from super resolution, optical trapping, to particle acceleration. The enormous freedom in metasurface design motivates the implementation of polarization control in ultrathin and compact optical systems. However, the majority of proposed strategies based on metasurfaces have been demonstrated only a spatially homogeneous polarization generation, while less attention has been devoted to spatially variant inhomogeneous vector beams. Here, we demonstrate a novel method for generating arbitrary radial and azimuthal polarization beams with high efficiencies of up to 80% by utilizing transmission-type dielectric metasurfaces. Polarization conversion metasurfaces are suitable candidates for the implementation of polarization encryption, which we demonstrate by encoding a hidden image into the spatial polarization distribution. In addition, we show that the image pattern can be modified by appropriate polarization selection of the transmitted light. Such a method may provide a practical technique for a variety of applications such as imaging, encryption and anti-counterfeiting.

physics.optics↗

arXiv2019

Ultrafast decoupling of atomic sublattices in a charge-density-wave material

Atomic rearrangements within crystals lie at the foundation of electron-phonon-coupled phenomena such as metal-insulator transition and superconductivity. Advanced laser-pump-probe studies have recently focused on various charge-density-wave (CDW) materials to sharpen our understanding of the charge-lattice entanglement, where non-thermal melting of the CDW state is evident from the enhanced Bragg diffraction peak intensities - attributed to the dominance of the metal-atom dynamics over the nonmetal-anion one. Here using ultrafast MeV electron diffraction on the prototypical CDW material 1T-TaSeTe, we observe an unusual coexistence of systematically enhanced and suppressed Bragg peak intensities upon the CDW suppression, indicating a dominance of nonmetal-anion dynamics during photoexcitation. By tracking these atomic trajectories quantitatively through the ultrafast process, we identify a transient state that manifests itself as an unexpected decoupling of the Ta and Se/Te sublattices. These findings unambiguously unveil a new kind of laser manipulations of lattice order parameters, which has potentials in creating new quantum states and discerning hidden phases such as intra-unit-cell orders.

cond-mat.mtrl-sci↗

arXiv2018

Ultrahigh Magnetic Fields Produced by Shearing Carbon Nanotubes

In laboratories, ultrahigh magnetic fields are usually produced with very large currents through superconducting, resistive or hybrid magnets, which require extreme conditions, such as low temperature, huge cooling water or tens of megawatts of power. In this work we report that when single walled carbon nanotubes (SWNTs) are cut, there are magnetic moments at the shearing end of SWNTs. The average magnetic moment is found to be 41.5+-9.8uB per carbon atom in the end states with a width of 1 nm at temperature of 300.0K, suggesting ultrahigh magnetic fields can be produced. The dangling sigma and pi bonds of the carbon atoms at the shearing ends play important roles for this unexpectedly high magnetic moments because the oxidation temperature of cut SWNTs is found to be as low as 312 in dry air. Producing ultrahigh magnetic field with SWNTs has the advantage of working at higher working temperature and with low energy consumption, suggesting great potentials of applications.

cond-mat.mtrl-sci↗

arXiv2018

Generating Spatial Spectrum with Metasurfaces

Fourier optics, the principle of using Fourier Transformation to understand the functionalities of optical elements, lies at the heart of modern optics, and has been widely applied to optical information processing, imaging, holography etc. While a simple thin lens is capable of resolving Fourier components of an arbitrary optical wavefront, its operation is limited to near normal light incidence, i.e. the paraxial approximation, which put a severe constraint on the resolvable Fourier domain. As a result, high-order Fourier components are lost, resulting in extinction of high-resolution information of an image. Here, we experimentally demonstrate a dielectric metasurface consisting of high-aspect-ratio silicon waveguide array, which is capable of performing Fourier transform for a large incident angle range and a broad operating bandwidth. Thus our device significantly expands the operational Fourier space, benefitting from the large numerical aperture (NA), and negligible angular dispersion at large incident angles. Our Fourier metasurface will not only facilitate efficient manipulation of spatial spectrum of free-space optical wavefront, but also be readily integrated into micro-optical platforms due to its compact size.

physics.optics↗

arXiv2017

Speed-dependent ice bandings in freezing colloidal suspensions

Formation mechanism of speed-dependent ice bandings in freezing colloidal suspensions, of significance in frost heaving and materials science, remains a mystery. With quantitative experiments, we propose a possible mechanism of speed-dependent ice bandings by focusing on the particle packing density and dynamic interface undercooling. The particle packing density ahead of the freezing interface decreases with increasing pulling speeds, attributed to the speed-dependent packing of particles. Through affecting the curvature undercooling of pore ices, the speed-dependent packing of particles can be used to explain speed-dependent thicknesses of ice bandings. The dynamic interface undercooling was obtained to explore curvature undercooling of pore ices and quantitative details of transient interface positions, speeds and undercooling were given. All the evidences imply that the speed-dependent particle packing and dynamic interface undercooling are responsible for speed-dependent ice bandings.

cond-mat.mtrl-sci↗