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arXiv · 2503.01186

Huge Stress-induced Adiabatic Temperature Change in a High-Toughness All-d-metal Heusler Alloy

Rui Cai·Zhiyang Wei·Hongjie Ren·Hanyang Qian·Xinyu Zhang·Yao Liu·Xiang Lu·Wen Sun·Meng Gao·Enke Liu·Jian Liu·Guowei Li
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Abstract

The elastocaloric effect (eCE), referring to the thermal effect triggered by a uniaxial stress, provides a promising and versatile routine for green and high efficient thermal management. However, current eCE materials generally suffer from relatively low eCE and poor mechanical properties, hindering their practical applications. Here, we report a exceptionally huge eCE with a directly measured adiabatic temperature change of up to 57.2 K in a dual-phase all-d-metal Heusler Mn50Ni37.5Ti12.5 polycrystalline alloy, revealing an extra contribution to the latent heat during the stress-induced martensitic transformation from B2 to L10, and breaking the record of adiabatic temperature change for elastocaloric alloys. Moreover, thanks to the combined strengthening effect of d-d hybridization and well-dispersed secondary cubic γ phase, the alloy can endure a uniaxial stress up to 1760 MPa. Such an abnormal huge eCE is attributed to the combination of the enhanced entropy change associated with a stress-induced B2 to L10 martensitic transformation under higher stress, in contrast with the thermally induced B2 to 5-layer modulated structure one, and the high transformation fraction due to the multi-point nucleation facilitated by the γ phase dispersed in the main phase. This work provides insight into making full use of the transformation heat to enhance the caloric effect for high-efficient thermal management systems.

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Rui Cai, Zhiyang Wei, Hongjie Ren, Hanyang Qian, Xinyu Zhang, Yao Liu, Xiang Lu, Wen Sun, Meng Gao, Enke Liu, Jian Liu, Guowei Li. 2025-03-03. Huge Stress-induced Adiabatic Temperature Change in a High-Toughness All-d-metal Heusler Alloy. https://arxiv.org/abs/2503.01186

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